KINETICS OF THE THERMAL DISSOCIATION OF N2F4 IN SHOCK WAVES,

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Abstract:

The equilibrium dissociation of N2F4 to 2NF2 was studied in schock waves, yielding an equilibrium constant identical to those obtained previously in static measurements. The thermal dissociation rate for N2F4 diluted with argon, helium and SF6 was studied between 350 K and 450 K at total pressures of 0.58 to 2.7 atmospheres. The reaction was found to be first order, indicating a bimolecular mechanism. The rate constants are discussed in terms of collision theory. Author

Author(s):
Modica, A. P. ; Hornig, D. F.
Author Organization(s):
PRINCETON UNIV N J FRICK CHEMICAL LAB
Pagination:
0001

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR4
Contract/Grant Number(s):
NONR185826
Project Number(s):
NR357 275
 Subject Terms
Joint Capability Areas:
JCA_3.2_Engagement; JCA_3_Force Application
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*HYDRAZINE DERIVATIVES, REACTION KINETICS), SHOCK WAVES, DISSOCIATION, HYDRAZINE DERIVATIVES, FLUORINE COMPOUNDS, THERMODYNAMICS, GASES, ARGON, HELIUM, SULFUR COMPOUNDS, NITROGEN COMPOUNDS
Report Date:
1963 Oct 31