FUSIBILITY DIAGRAMS IN THE SYSTEMS LiClO4 Ca(ClO4)2 AND NaClO4 - Ca(ClO4)2
Abstract:
The systems LiClO4 - CaClO42 and NaClO4 CaClO42 were studied. The fusibility diagram in both systems is characterized by a simple eutectic and by polymorphic transitions of the components. Forming compounds these systems was unsuccessful. In the system NaClO4 - CaClO42 in the region rich in sodium perchlo rate, the existence of two solid solutions is proved. On the basis of thermographic study of calcium perchlorate and a study of systems derived from it data were obtained which indi cated the presence of three polymorphic modifi cations of calcium perchlorate with transition points at 342 and 406 C.
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