IONIC FLUORINE CHEMISTRY.

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Abstract:

The reaction of chlorine pentafluoride with cesium fluoride to form cesium hexafluorochlorate has been investigated, and results obtained during an earlier Olin-sponsored study have been confirmed. The weight gain of the cesium fluoride and the high ratio of F to Cl in the product as indicated by elemental analysis permit calculations which suggest a composition consisting of CsClF6, CsClF4, CsHF2 and unreacted CsF. Instrumental methods of analysis are being applied in the effort to establish characteristic patterns of the ClF6 anion. Preliminary results from the reaction of NOFClF5 with CsF indicate that this may be a way to produce product free of CsClF4 when ClF5 free of ClF3 is used. Author

Author(s):
Hyde, G. A. ; Trotz, S. I.
Author Organization(s):
OLIN MATHIESON CHEMICAL CORP NEW HAVEN CONN CHEMICALS GROUP
Descriptive Note:
Semiannual status rept. no. 1, 1 May-30 Nov 67,
Pagination:
0013

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
NH-2649
Contract/Grant Number(s):
N00014-67-C-0435
Project Number(s):
RR-001-06-02, NR-093-048
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
*FLUORINE, *IONS, *OXIDIZERS, *CHLORINE COMPOUNDS, *FLUORIDES, *CESIUM COMPOUNDS, CHEMICAL PROPERTIES, CHEMICAL REACTIONS
Field(s)/Group(s):
Inorganic Chemistry
Keyword(s):
CESIUM FLUORIDE, CHLORINE PENTAFLUORIDE
Report Date:
1967 Dec 10