RESEARCH IN FLUORO-NITRO COMPOUNDS

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Abstract:

The reaction of alpha,alpha-dibromo-alpha-nitrotoluene with NHF2 and fuming H2sO4 gave alpha, alpha-dibromo-alpha-difluoraminotoluene as well as alpha-bromo-alpha,alpha-bisNF2toluene. Alpha-NF2-alpha,alpha-dichlorotoluene was prepared from alpha,alpha,alpha-trichlorotoluene and NHF2. Alpha,alpha- dibromo-alpha-difluoraminotoluene, alpha-bromo-alpha,alpha-bisNF2toluene and alpha-NF2-alpha,alpha-dichlorotoluene each reacted with methanolic sodium methoxide to give dimethyl carbonate anil. Butyldifluoramine and sec- butyldifluoramine were obtained in 4050 yields by the direct fluorination of nbutylurea and methyl sec-butylcarbamate, respectively, in acetonitrile solution. Direct fluorination of aqueous 3-hydroxypropylformamide gave 3- difluoraminopropyl formate. Preliminary results on the fluorination of aldoximes are presented. The preparation of fluoroammonium perchlorate was scaled-up to 2- 3 g batches.

Author(s):
Baum, K. ; Grakauskas, V. ; Remanick, A. H. ; Schaeffler, O. S.
Author Organization(s):
AEROJET-GENERAL CORP AZUSA CA
Descriptive Note:
Quarterly technical summary rept. no. 21, 1 Oct-31 Dec 1964
Pagination:
0031

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release, Document Partially Illegible
Distribution Statement:
Approved For Public Release; Distribution Is Unlimited. Document Partially Illegible.

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
AGC-0235-01-21
Contract/Grant Number(s):
NONR-2655(00), ARPA ORDER-170-7
Monitor Series:
DARPA
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management; JCA_6_Net Centric; JCA_6.3_Net Management; JCA_5.3_Planning; JCA_5_Command and Control; JCA_3.2_Engagement; JCA_3_Force Application
Modernization Areas:
Fully Networked C3
Communities of Interest:
Weapons Technologies
Descriptor(s):
*NITROGEN COMPOUNDS, *OXIDIZERS, AMMONIUM COMPOUNDS, AROMATIC COMPOUNDS, BROMINE COMPOUNDS, CHLORINE COMPOUNDS, CRYSTALLIZATION, FLUORINATION, FLUORINE COMPOUNDS, FLUOROAMINES, FORMATES, INFRARED SPECTRA, NITRATES, NUCLEAR MAGNETIC RESONANCE, ORGANIC NITROGEN COMPOUNDS, OXIMES, PERCHLORATES, PRODUCTION, PURIFICATION, PYROLYSIS, SYNTHESIS(CHEMISTRY)
Field(s)/Group(s):
Organic Chemistry
Keyword(s):
AMMONIUM PERCHLORATE FLUORO, BUTYRATE 2 3 BIS(DIFLUOROAMINO)
Report Date:
1965 Feb 01