MOLECULAR ORIGINS OF PRODUCTS OF REACTION OF PROPYLENE WITH ACTIVE NITROGEN

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Abstract:

The molecular origins of HCN, C2H2, C2H4, C2H6, C3H8 and CH3CN formed by the reaction of active nitrogen with propylene were investigated by determining the relative molar radioactivities of these products when formed respectively from each of the three propylenes labeled specifically at a single skeletal atom with C. The results establish that none of the C2 products arise from unique sites in the propylene molecule nor are any of them the result of random incorporation of carbon. The degradative processes responsible for their formation are apparently highly complex. Author

Author(s):
Lichtin, Norman N. ; Shinozaki, Yoshiharu
Author Organization(s):
BOSTON UNIV MASS
Annotation:
MOLECULAR ORIGINS OF HCN, C2H2, C2H6, C3H8, CH3CN PRODUCED FROM THE REACTION OF ACTIVE N WITH PROPYLENE. RELATIVE RADIOACTIVITIES OF PRODUCTS FROM 3 PROPYLENES EACH LABELED AT A SPECIFIC CARBON ATOM.
Pagination:
0001

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Subject Terms
Communities of Interest:
Materials and Manufacturing Processes
Descriptor(s):
*DECOMPOSITION, *NITROGEN, *PROPENES, ACETYLENES, ATOMS, CHEMICAL REACTIONS, CYANIDES, DEGRADATION, DEUTERIUM COMPOUNDS, ETHANES, ETHYLENES, HYDROCARBONS, HYDROGEN COMPOUNDS, METHYL RADICALS, PROPANE, REACTION KINETICS, VINYL RADICALS
Keyword(s):
VINYL RADICALS, PROPANES (3 C), METHYL RADICALS, ETHANES, ACETYLENES (C C)
Report Date:
1962 Apr 03