STUDY LEADING TO THE DEVELOPMENT OF POLYMERS FOR USE IN HIGH TEMPERATURES

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Abstract:

The reaction of sulfamic acid with PCl5, either in the absence or in the presence of a small quantity of CCl4 as a solvent, is an advantageous method for the synthesis of trichlorophosphazosulfonyl chloride. The latter material is an essential intermediate for the preparation of the trimer of sulfanuric chloride. Reactions of bis-trichlorophosphazosulfone and of the chlorides of N,N-dialkylsulfamido-N-phosphoric acid with Grignard reagents have lead to compounds in which the Cl atoms are all replaced by aryl groups. Thus far, only phenylmagnesium bromide has been caused to react with the corresponding chlorides. The synthesis of the unknown tribromophosphazosulfonyl bromide, by reaction of sulfamic acid with PBr3 and Br in CCl4 or stetrachloroethane as solvents, has been also attempted. Author

Author(s):
Moeller, Therald ; Vandi, Antonio
Author Organization(s):
ILLINOIS UNIV URBANA
Pagination:
0001

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Contract/Grant Number(s):
DA11 022ORD2956
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
*HEAT RESISTANT PLASTICS, *SULFAMIC ACIDS, *SULFONES, *SULFONYL RADICALS, BENZENE, BROMIDES, BROMINE COMPOUNDS, CHLORIDES, DECOMPOSITION, MAGNESIUM COMPOUNDS, ORGANOMETALLIC COMPOUNDS, PHENYL RADICALS, PHOSPHONIC ACIDS, PHOSPHORUS COMPOUNDS, POLYMERS, SULFONAMIDES, SULFUR COMPOUNDS, SYNTHESIS
Keyword(s):
*SULFONYL (O S O), PHENYL RADICALS, SULFONAMIDO (S02N), *SULFONES
Report Date:
1961 May 01