The Donor Properties of Pyridine-N Oxide

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Abstract:

The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated. The new substances CoClO42.6L, CoNO32.6L, CoCl2.3L, CoCl2.L.H20, NiClO42.6L, NiCl2.L.H2O, NiBr2.6L, NiI2.6L, NiBr2.L. H2O, CuClO42.4L, CuNO32.2L, CuCl2.L, CuCl2.2L, ZnClO42.6L, ZnCl2.2L, ZnNO32.6L, FeClO42.6L, FeClO43.6L, and SnBr4.2L where L is pyridine N-oxide have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra. All of the perchlorates and some of the nitrates and halides have only the pyridine N-oxide in the first coordination sphere. However, in some cases, both nitrates and halides are coordinated to the central ion.

Author(s):
Franz, G. ; Fujita, J. ; Phillips, D. J. ; Quagliano, J. V. ; Tyree, S. Y. ; Walmsley, J. A.
Author Organization(s):
NORTH CAROLINA UNIV AT CHAPEL HILL DEPT OF CHEMISTRY
Descriptive Note:
Technical rept. no. 6
Pagination:
0018

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release
Distribution Statement:
Approved For Public Release; Distribution Is Unlimited.

RECORD

Collection: TR
Identifying Numbers
Contract/Grant Number(s):
NONR-855(05)
Project Number(s):
NR-052-371
Monitor Series:
ONR
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management; JCA_6_Net Centric; JCA_6.3_Net Management; JCA_5_Command and Control; JCA_1.2_Force Preparation; JCA_1_Force Support; JCA_5.3_Planning; JCA_1.2.3_Educating
Modernization Areas:
Microelectronics
Communities of Interest:
No COI(s) Identified
Descriptor(s):
*COMPLEX COMPOUNDS, *PYRIDINES, BROMIDES, CHLORIDES, COBALT COMPOUNDS, COPPER COMPOUNDS, CRYSTAL STRUCTURE, ELECTRICAL CONDUCTIVITY, INFRARED SPECTROSCOPY, IODIDES, IRON COMPOUNDS, MAGNETIC PROPERTIES, NICKEL COMPOUNDS, NITRATES, OXIDES, PERCHLORATES, SOLVATION
Field(s)/Group(s):
Organic Chemistry
Report Date:
1961 Feb 01