Notes on the Preparation and Analysis of Halogenide-Free Rhodium(III) Perchlorate (Sulfate) Solutions

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Abstract:

A method is described for the preparation of halogenide-free rhodiumIII perchlorate sulfate solutions. As starting material, rhodium chloride or rhodium bromide can be used. The halogenide was removed by means of ozone, which oxidizes free not complex-bound halogenide to halogen and RhIII to RHV O3 2X- 2H yields RhV O2 H2O 1 X Cl or Br RhIII O3 2H yields RhV O2 H2O 2. The RhV produced, being a strong oxidizing agent, also reacts with the halogenide according to RhV 2X- yields RhIII X2 3. Methods for the detection of halogenide-ions in rhodium solutions are given.

Author(s):
Berecki-biedermann, Clara
Author Organization(s):
STOCKHOLM UNIV (SWEDEN) DEPT OF INORGANIC CHEMISTRY
Descriptive Note:
Technical note no. 2
Pagination:
0015

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release
Distribution Statement:
Approved For Public Release; Distribution Is Unlimited.

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
AFCRL-TN-60-462
Contract/Grant Number(s):
AF 61(052)-181
Monitor Series:
TN-60-462, AFCRL
 Subject Terms
Joint Capability Areas:
JCA_1.2.7_Experimentation
Communities of Interest:
No COI(s) Identified
Descriptor(s):
*PERCHLORATES, *RHODIUM COMPOUNDS, *SULFATES, CHEMICAL ANALYSIS, CHEMICAL REACTIONS, HALIDES, IONS, OZONE, SOLUTIONS(MIXTURES), SOLVATION, SWEDEN, SYNTHESIS, VALENCE
Field(s)/Group(s):
Inorganic Chemistry
Keyword(s):
FOREIGN REPORTS
Report Date:
1960 Feb 15