DID YOU KNOW? DTIC has over 3.5 million final reports on DoD funded research, development, test, and evaluation activities available to our registered users. Click
HERE to register or log in.
Accession Number:
ADA067603
Title:
Photoactivation of Organometallic Catalysts.
Corporate Author:
MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY
Report Date:
1979-04-03
Abstract:
Photochemistry offers a technique to synthesize unique catalysts, control catalytic reactions, and perturb and better understand conventional catalytic cycles. Recent studies in the authors laboratory concerning photoinduced catalysis using mono-, di-, and trinuclear organometallic catalyst precursors are summarized. Specific systems considered here are MCOnL5-n M Fe, Ru L PPh n 5,4,3, M3CO12 M Fe, Ru, Os, Ru3COgPPh33, and Co2CO6L2 L Pn-Bu3, POPh3 used to effect catalytic chemistry of 1-pentene including isomerization, hydrogenation, and hydrosilation. Author
Descriptive Note:
Technical rept.,
Pages:
0043
Contract Number:
N00014-75-C-0880
File Size:
16.29MB
