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Accession Number:
ADA067596
Title:
Photochemistry and Electronic Structure of Bis(dicarbonyl(pi5-Cyclopentadienyl)Ruthenium) and Its Iron Analogue.
Corporate Author:
MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY
Report Date:
1979-04-03
Abstract:
The photochemistry of a number of dinuclear metal-metal bonded organometallic complexes is dominated by cleavage of the metal-metal bond. This chemistry is in accord with lowest excited states which involve the population of an orbital which is strongly antibonding sigma with respect to the metal-metal bond. All of the complexes for which detailed studies have been reported involve systems for which the metal-metal bond is not bridged. A number of qualitative observations have been described which strongly implicate symmetrical cleavage reactions of bridged systems subsequent to electronic excitation.
Descriptive Note:
Interim technical rept.,
Pages:
0028
Contract Number:
N00014-75-C-0880
File Size:
10.98MB
