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Accession Number:
AD0701754
Title:
KINETICS OF SYNTHESIS AND DECOMPOSITION REACTIONS OF IONIC COMPOUNDS CONTAINING N-F CATIONS.
Corporate Author:
IIT RESEARCH INST CHICAGO ILL
Report Date:
1970-02-13
Abstract:
Kinetic studies have been made of the decomposition of NF4AsF6 in a Monel system. The data are interpreted in terms of an equilibrium dissociation. Values for the product K1Keq are presented for the range 175 to 240C, from which the sum delta Hs Ea is found to be 50 kcalmole. Preliminary results from a matrix isolation study of the decomposition of NF4AsF6 indicate that, besides NF3 and AsF5 a small amount of an unidentified compound is present. The new lines have not yet been correlated with the spectrum of any known compound. Ammonium perbromate, NH4BrO4, has been prepared, and some of its physical and chemical properties examined. It is rather similar to NH4ClO4, though somewhat less stable. Author
Descriptive Note:
Annual summary rept. 1 Feb 69-31 Jan 70,
Supplementary Note:
See also Report no. IITRI-C6140-2, AD-682 497.
Pages:
0027
Contract Number:
N00014-68-C-0279
File Size:
0.00MB
