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Accession Number:
AD0623781
Title:
EFFECT OF A FERROCENYL SUBSTITUTE ON THE FUNCTIONAL GROUPS IN THE BENZENE RING,
Corporate Author:
FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO
Report Date:
1965-01-01
Abstract:
The dissociation constants K-a and K-b were obtained for several ferrocenyl substituted benzoids and were compared with these constants for amino and hydroxy substituted benzoids. The K-b of p-Ferrocenylaniline is 3 times greater than that of aniline, and 17 times greater than that of p-aminodiphenyl xenylamine the K-b of m-ferrocenylanaline is 23 as great as the p- isomer. Similar results were obtained by the comparison of ferrocenylamine and ferrocenylphenol with phenol and p-hydroxydiphenyl p-phenylphenol, indicating that the ferrocenyl group introduced into the benzene ring behaves as a distinctly expressed substitute of the first order.
Supplementary Note:
Vliyanie Ferrotsenilnogo Zamestitelya na Funktsionalnye Gruppy v Benzolnom Yadre, trans. of Akademiya Nauk SSSR, Doklady, v103 n1 p81-2 1955.
Pages:
0004
File Size:
0.00MB
