Accession Number:

AD0612245

Title:

THE THERMAL DECOMPOSITION OF METAL COMPLEXES. XIII. SOME TETRAMMINEPALLADIUM(II) COMPLEXES,

Personal Author(s):

Corporate Author:

TEXAS TECHNOLOGICAL COLL LUBBOCK

Report Date:

1964-02-07

Abstract:

The thermal dissociation of the palladiumII tetramminecomplexes, PdNH34X where X is 2Cl, 2Br, 2I, 2NO3, and SO4, was studied by thermogravimetry, DTA, GE, and by analysis of the pyrolysis products. The complexes, except for the nitrate and sulphate, dissociated to give the trans-diammine-complexes, PdNH32X. The diammine-iodide and bromide complexes dissociated to give the corresponding anhydrous metal halides, PddX2. The stoicheiometry for the thermal dissociation of the PdNH32X2 complexes, where X was Cl, Br, and I, was determined. Author

Supplementary Note:

Pub. in Journal of Inorganic and Nuclear Chemistry (Gt. Brit.) v26 p1879-84 1964 (Copies available only to DDC users).

Pages:

0007

Contract Number:

AF AFOSR23 63

File Size:

0.00MB

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