Accession Number:

AD0610382

Title:

Semiconducting Materials: Part 2 AnInvestigation of the Boron-Phosphorous System

Personal Author(s):

Corporate Author:

NEW YORK STATE COLL OF CERAMICS ALFRED

Report Date:

1965-01-15

Abstract:

Hot-pressing of BP was used to prepare polycrystal line samples in the boron-phosphorous system. Hotpressed samples containing up to 24 carbon were also prepared and their properties analyzed. A study of the effect of hot- pressing variables on composition and properties was made. A comprehensive analysis was made of compounds, phases, compositions, grain size, and impurity content. A series of compositions, including pure B13P2, was examined for Knoop hardness, electrical conductivity, activation energies, thermal conductivity, thermoelectric power, density, Hall effect, and magnetoresistance. The value of hot-pressed samples in the boron-phosphorouscarbon system for thermoelectric applications was measured and reviewed. The electrical conductivity in B13P2 was measured and a mechanism for conduction based on extrinsic levels and a surface effect is proposed. A theoretical model for understanding the physical aspects of this system is presented. Sufficient evidence of the existence of B10P was obtained to warrant further study. A correlation between composition and physical properties was established.

Descriptive Note:

Final rept. Pt. 2

Pages:

0267

Identifiers:

Communities Of Interest:

Modernization Areas:

Distribution Statement:

Approved for public release; distribution is unlimited.

Contract Number:

NONR-50301

File Size:

12.83MB