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SOME APPLICATIONS OF TCHEBYCHEV'S INEQUALITY TO ANALYSIS
RUTGERS - THE STATE UNIV NEW BRUNSWICK N J
OXFORD U. Gt. Brit.. THE REACTION OF ATOMS AND RADICALS WITH VARIOUS MOLECULES. Technical final rept., 1 Feb 57-31 Oct 61, by J. W. Linnett. 26 Nov 61, 12p. Contract AF 615141117 AFOSR-2029Unclassified report DESCRIPTORS Combustion, Flames, Organic compounds, Atoms, Free radicals, Chemical reactions, Controlled atmospheres, Nitrogen, Oxygen, Spectrographic analysis. Recombina tion reactions, Catalysis, Reaction kinetics, Atoms, Oxygen, Hydrogen. Catalysts, Sil icon compounds, Dioxides, Nickel compounds, Oxides, Gold, Palladium, Gold alloys, Palladium alloys. Alloys. Emission spectra from flames of organic substances burning in active nitrogen at low pressures revealed a group of bands near 3290 angstroms only when the organic material contained H. Further analysis indicated that the emitter contained C and N and at least 3 atoms. From experiments with isotopic C, it was shown that the emitter was NCN. It was found that only the 4315 angstrom system of the CH emission is observed in flames supported by N atoms when atomic O is used, the 3889 angstrom system is observed as well. Recombination of O and H atoms on the surfaces of catalysts, and the recombination of O atoms in the gas phase are discussed. Author