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Accession Number:
AD0271791
Title:
COCRYSTALLIZATION OF ULTRAMICRO QUANTITIES OF IRON AND OTHER ELEMENTS WITH OXINE GENERATED IN SITU
Corporate Author:
NAVAL RADIOLOGICAL DEFENSE LAB SAN FRANCISCO CA
Report Date:
1961-10-31
Abstract:
The cocrystallization of Fe in trace quantities with oxine formed homogeneously in solution by the hydrolysis of 8-acetoxyquinoline was studied. The distribution of microcomponent between the solid phase and the mother liquor was profoundly affected by the degree of supersaturation. After relief from supersaturation, a constant distribution coefficient was calculated by an equation which was predicated upon the Doerner-Hoskins equilibrium. The cocrystallization of other elements was also examined with an arbitrarily established set of conditions. Pu, Ce, and Pr were quantitatively recovered from solution.
Supplementary Note:
DOI: 10.21236/AD0271791
Pages:
0030
Distribution Statement:
Approved for public release; distribution is unlimited.
File Size:
1.08MB