Accession Number:

AD0271791

Title:

COCRYSTALLIZATION OF ULTRAMICRO QUANTITIES OF IRON AND OTHER ELEMENTS WITH OXINE GENERATED IN SITU

Personal Author(s):

Corporate Author:

NAVAL RADIOLOGICAL DEFENSE LAB SAN FRANCISCO CA

Report Date:

1961-10-31

Abstract:

The cocrystallization of Fe in trace quantities with oxine formed homogeneously in solution by the hydrolysis of 8-acetoxyquinoline was studied. The distribution of microcomponent between the solid phase and the mother liquor was profoundly affected by the degree of supersaturation. After relief from supersaturation, a constant distribution coefficient was calculated by an equation which was predicated upon the Doerner-Hoskins equilibrium. The cocrystallization of other elements was also examined with an arbitrarily established set of conditions. Pu, Ce, and Pr were quantitatively recovered from solution.

Supplementary Note:

DOI: 10.21236/AD0271791

Pages:

0030

Identifiers:

Subject Categories:

Communities Of Interest:

Modernization Areas:

Distribution Statement:

Approved for public release; distribution is unlimited.

File Size:

1.08MB