DID YOU KNOW? DTIC has over 3.5 million final reports on DoD funded research, development, test, and evaluation activities available to our registered users. Click
HERE to register or log in.
Accession Number:
AD0245504
Title:
Notes on the Preparation and Analysis of Halogenide-Free Rhodium(III) Perchlorate (Sulfate) Solutions
Corporate Author:
STOCKHOLM UNIV (SWEDEN) DEPT OF INORGANIC CHEMISTRY
Report Date:
1960-02-15
Abstract:
A method is described for the preparation of halogenide-free rhodiumIII perchlorate sulfate solutions. As starting material, rhodium chloride or rhodium bromide can be used. The halogenide was removed by means of ozone, which oxidizes free not complex-bound halogenide to halogen and RhIII to RHV O3 2X- 2H yields RhV O2 H2O 1 X Cl or Br RhIII O3 2H yields RhV O2 H2O 2. The RhV produced, being a strong oxidizing agent, also reacts with the halogenide according to RhV 2X- yields RhIII X2 3. Methods for the detection of halogenide-ions in rhodium solutions are given.
Descriptive Note:
Technical note no. 2
Pages:
0015
Distribution Statement:
Approved for public release; distribution is unlimited.
Contract Number:
AF 61(052)-181
File Size:
0.49MB
