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Conductive Polymers of Transition-Metal Complexes Coordinated by a Diamino-Dichalcogen-Benzene Compound.
Patent, Filed 28 Mar 88, patented 29 Aug 89,
DEPARTMENT OF THE NAVY WASHINGTON DC
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Polymeric metal complexes were prepared by coordination reactions of 2,5-diamino-1,4-benzenedithiol DADT with divalent metal halides cobalt chloride, iron chloride, copper chloride and nickel chloride in an aqueous alkaline solution at reflux temperatures. A black precipitate which conducted electricity was formed. Resistivity of the material increased upon exposure to air but decreased when oxygen was removed from the material. Patents. AW
APPROVED FOR PUBLIC RELEASE