Accession Number:
ADD014055
Title:
4-Azido-4,4-Dinitro-10Butanol and Derivatives Thereof.
Descriptive Note:
Patent, filed 5 Aug 87, patented 3 Jan 89,
Corporate Author:
DEPARTMENT OF THE AIR FORCE WASHINGTON DC
Personal Author(s):
Report Date:
1989-01-03
Pagination or Media Count:
4.0
Abstract:
There is provided the compound 4-azido-4,4-dinitro-1-butanol ADNBOH and a method for making same which comprises reacting trinitromethane and acrolein at a reduced temperature to provide 4,4,4-trinitrobutyraldehyde TNBA1, reducing the TNBSI to provide 4,4-trinitro-1-butanol TNBOH which is further reduced to provide 4,4-dinitro-1-butanol DNBOH, reacting the DNBOH with acetyl chloride to provide 4,4-dinitro-1-butyl acetate DNBAc, reacting the DNBAc with an alkali metal azide in an electrolysis cell to provide 4-azido-4,4-dinitro-1-butyl acetate ADNBAc and reacting the ADNBAc with a lower alcohol and recovering the 4-azido-4,4-dinitro-1-butanol ADNBOH. Also provided are several azidodinitro derivatives of 4-azido-4,4-dinitro-1-butanol and methods for making same. Butanol, Nitro radicals, Azides. Patents. mjm
Descriptors:
Subject Categories:
- Organic Chemistry