Accession Number:

ADA581116

Title:

3,3'-(1-Oxopropane-1,3-diyl)bis(1,3-thiazolidine-2-thione) Chlorobenzene Hemisolvate

Descriptive Note:

Journal article

Corporate Author:

NAVAL RESEARCH LAB WASHINGTON DC CHEMISTRY DIV

Personal Author(s):

• Franzel, Christine
• Purdy, Andrew
• Butcher, Ray J.

Report Date:

2013-01-01

Pagination or Media Count:

9.0

Abstract:

The title compound, C9H12N2OS40.5C6H5Cl, which contains two 1,3-thiazolidine-2-thione rings, is a by-product of the synthesis of 3-acryloyl-1,3-thiazolidine-2-thione. The dihedral angle between these rings is 79.95 9 deg., with both rings displaying a twisted conformation. The twist angle of the amide group is 5.6 1 deg. In the crystal, the molecules are linked into 001 chains by C--H...O interactions. The chlorobenzene solvent molecule was found to show unresolvable disorder about a centre of inversion and its contribution to the scattering was removed with the SQUEEZE option in PLATON Spek 2009. Acta Cryst. D65, 148 155.

Descriptors:

• *CHLOROBENZENE
• AMIDES
• CRYSTALS
• INTERACTIONS
• MOLECULES
• REPRINTS
• SOLVATES
• SYNTHESIS(CHEMISTRY)

Subject Categories:

• Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE