Accession Number:

ADA467786

Title:

Solid State Synthesis Under Supramolecular Control of a 2D Heterotetratopic Self-complementary Tecton Tailored to Halogen Bonding

Descriptive Note:

Journal article

Corporate Author:

POLITECNICO DI MILANO (ITALY)

Report Date:

2006-07-31

Pagination or Media Count:

7.0

Abstract:

We describe the synthesis and characterization, by single crystal X-ray analysis, of a 1D heteroditopic self-complementary tecton for halogen bonding. It was designed to also incorporate double bonds and to possess heteropolar pi-pi stacking groups in order to carefully control its supramolecular organization in the solid state. As a result of this supramolecular control, by UV irradiation in the solid state the compound dimerizes forming a 2D heterotetratopic self-complementary tecton tailored to halogen bonding based self-assembly. This 2D tecton crystallizes clathrating chloroform molecules.

Subject Categories:

  • Physical Chemistry
  • Crystallography

Distribution Statement:

APPROVED FOR PUBLIC RELEASE