Accession Number:

ADA422707

Title:

Effect of Ligand Coordination on Complex Formation: Synthesis and Structural Studies of Metal(I) Salts Containing the N(SO2CF3)2 and OTeF5 Groups

Descriptive Note:

Corporate Author:

ENGINEERING RESEARCH AND CONSULTING INCHUNTSVILLE AL

Report Date:

2004-03-23

Pagination or Media Count:

40.0

Abstract:

The cisoid form is less common. In the CCDC, only 6 structures show this conformation where as the transiod form occurs in 15 remaining structures The cisoid conformation results from stronger cation-anion interaction The cisoid exclusively when anion is chelated to the metal center The transoid form dominates in structures containing a free anion NO structure known with both cisoid AND transoid geometry

Subject Categories:

  • Physical Chemistry
  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE