Accession Number:

ADA422509

Title:

Polynitrogen Chemistry: Recent Development in Pentazole and Polyazide Chemistry

Descriptive Note:

Technical Paper(view graph)

Corporate Author:

ENGINEERING RESEARCH AND CONSULTING INC(ERC INC) EDWARDS AFB CA

Report Date:

2004-03-24

Pagination or Media Count:

18.0

Abstract:

Partial contents Polynitrogen Chemistry Recent Development in Pentazole and Polyazide Chemistry, Why Polynitrogen Compounds, Geometry of the N5 cation , In Compatabillty of N5, New Polynitrogen Anions as Counterparts for N5, Synthetic Challenge How do we make These New Anions, Formation and Stabillty of Sllyl Diazonium Salts, Synthesis of Aryldiazonium Salts, Pentazole Formation.. Not a Trivial Chore, Identification of Arylpentazoles, Cleavage of the Aryl-Pentazole Bond with Retention of the Pentazole Ring, MSMS of the Parent Ion Peak, Chemical Cleavage of the C-N Bond, Aryl-pentazole bond cleavage N5 anion in Solution, Subsequent Decomposition of the Pentazole Anion, Pentazoles with Heterocyclic Substituents, 15N NMR of 2-pentazoly-4, 5-dicyano- imidazole, Pentazolate Anion in Solution, Chronology of the Pentazolate Anion, What are normal N-N distances in azides, Abnormalities in azide distances Artifacts or Structural Contaminants, Reactivity of hexachioroantimonate VI - with Trimethylsilylazide, The tetraphenylarsonium antimonychioride azide case.

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE