Accession Number:

ADA416766

Title:

Polynitrogen Chemistry. Preparation and Characterization of (N5)2SnF6,N5SnF5, and N5B(CF3)4

Descriptive Note:

Technical paper rept.

Corporate Author:

ENGINEERING RESEARCH AND CONSULTING INC(ERC INC) EDWARDS AFB CA

Report Date:

2003-03-21

Pagination or Media Count:

22.0

Abstract:

The successful synthesis of the 21 salt N52SnF62- demonstrates that compounds with touching polynitrogen cations can be prepared, and that the synthesis of an ionic, all nitrogen compound is in principal possible. This paper also shows that N5 salts, other than N5SbF6 and N5AsF6, can be prepared by metathetical reactions. This method was applied to the syntheses of N5BCF34, N5SnF5, and N52SnF62-.

Subject Categories:

  • Inorganic Chemistry
  • Physical Chemistry
  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE