Accession Number:

ADA361693

Title:

Synthesis of Tetraazacrown Ethers Containing Two 8-Hydroxyquinoline Side Arms

Descriptive Note:

Technical rept.

Corporate Author:

BRIGHAM YOUNG UNIV PROVO UT DEPT OF CHEMISTRY AND BIOCHEMISTRY

Personal Author(s):

• Yang, Zhaoxia
• Bradshaw, Jerald S.
• Savage, Paul B.
• Krakowiak, Krzysztof E.
• Izatt, Reed M.

Report Date:

1999-04-06

Pagination or Media Count:

12.0

Abstract:

Four new tetraazacrown ethers containing two 8-hydroxyquinoline side arms were prepared first by reductive amination of 8-acetoxyquinolin-2-carbaldehyde with the appropriate tetraazacrown ether containing two microring NH functions. The resulting bis8-acetoxy-1-quinolinylmethyl-substituted tetraazacrown ethers were treated with 10 aqueous KOH followed by acid to form the N,N-bis8-hydroxy-2-quinolinylmethyl substituted tetraazacrown ethers.

Descriptors:

• *SYNTHESIS(CHEMISTRY)
• *CROWN ETHERS
• ALDEHYDES
• QUINOLINES
• HETEROCYCLIC COMPOUNDS

Subject Categories:

• Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE