Accession Number:

ADA318375

Title:

Synthesis of a Novel Indium-Nitrogen Cage Compound. Molecular Structure of ?NpIn(M-(NH)2C6H4!4(Np=CH2C(CH3)3).

Descriptive Note:

Technical rept.,

Corporate Author:

DUKE UNIV DURHAM NC DEPT OF CHEMISTRY

Personal Author(s):

• Rahbarnoohi, Hamid
• Wells, Richard L.
• Rheingold, Arnold L.

Report Date:

1996-10-30

Pagination or Media Count:

12.0

Abstract:

Reaction of the ligand 1,2-NH22C6H4 with InNp3 Np neopentyl CH2CCH33 afforded the tetrameric compound NpInu-NH2C6H44 which contains five-coordinate indium centers having square pyramidal geometry and an overall approximate tetrahedral symmetry.

Descriptors:

• *LIGANDS
• *MOLECULAR STRUCTURE
• *INDIUM
• SYNTHESIS
• INDIUM ALLOYS
• NITROGEN
• SYMMETRY
• GEOMETRY
• PYRAMIDS(GEOMETRY)

Subject Categories:

• Inorganic Chemistry
• Organic Chemistry
• Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE