Accession Number:

ADA295665

Title:

Syntheses, Characterization, Crystal and Molecular Structures and Solution Properties of Et2Ga(C5H5) and EtGa(C5H5) 2.

Descriptive Note:

Technical rept.,

Corporate Author:

STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY

Personal Author(s):

• Beachley, O. T., Jr.
• Rosenblum, Daniel B.
• Churchill, Melvyn R.
• Lake, Charles H.
• Krajkowski, Lynn M.

Report Date:

1995-06-19

Pagination or Media Count:

38.0

Abstract:

The compounds Et2GaC5H5 and EtGaC5H52 have been prepared by ligand redistribution reactions in pentane solution between appropriate quantities of GaEt3 and GaC5H53. Both compounds have been fully characterized by elemental analyses, X-ray structural studies, cryoscopic molecular weight studies in benzene solution, mass spectroscopic studies, 1H NMR studies of solutions and 1H NMR studies of the melts. Both compounds exist as pure single compounds in the solid state. jg

Descriptors:

• *CRYSTAL STRUCTURE
• *SOLUTIONS(GENERAL)
• *GALLIUM
• *MOLECULAR STRUCTURE
• *ETHYL RADICALS
• BENZENE
• METHYL RADICALS
• SYNTHESIS
• STRUCTURAL ANALYSIS
• MOLECULAR WEIGHT
• MELTS
• ORGANOMETALLIC COMPOUNDS
• MASS SPECTROSCOPY
• X RAYS
• PURITY
• HYDROCARBONS
• LIGANDS
• CRYOGENICS
• SOLID STATE CHEMISTRY
• PENTANES

Subject Categories:

• Organic Chemistry
• Inorganic Chemistry
• Physical Chemistry
• Crystallography
• Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE