Accession Number:

ADA288897

Title:

Thermodynamics of Electrolyte Solutions for Use in High Energy Lithium Batteries,

Descriptive Note:

Corporate Author:

SURREY UNIV GUILDFORD (UNITED KINGDOM) DEPT OF CHEMISTRY

Personal Author(s):

• Danil de Mamor, Angela F.

Report Date:

1994-01-01

Pagination or Media Count:

4.0

Abstract:

This report contains information regarding a Thermodynamic parameters for the complexation of 15-crown-5 and lithium salts at 288.15 K in order to assess the temperature effect on these processes. b Gibbs energies, enthalpies and entropies for the binding of lithium with 4-nitrobenzo-15-crown-5 in acetonitrile at the standard temperature. This part of research aims to investigate the effect of substituents on the complexing abilities of 15-crown-5 and lithium cations.

Descriptors:

• *THERMODYNAMICS
• *LITHIUM BATTERIES
• *ELECTROLYTES
• * HIGH ENERGY
• CATIONS
• TEMPERATURE
• SOLUTIONS(MIXTURES)
• ACETONITRILE
• PARAMETERS
• FLUORINE
• SALTS
• ENTHALPY
• GREAT BRITAIN
• LITHIUM COMPOUNDS
• BORATES
• ENTROPY
• NITROBENZENES

Subject Categories:

• Physical Chemistry
• Organic Chemistry
• Thermodynamics

Distribution Statement:

APPROVED FOR PUBLIC RELEASE