Accession Number:

ADA282766

Title:

Synthesis and Characterization of Neopentyl Indium Compounds: X-Ray Crystal Structures of (Me3CCH2)2InAs(SiMe3)22 and (Me3CCH2)2InAs(SiMe3)2In(CH2CMe3)2C1

Descriptive Note:

Technical rept.

Corporate Author:

DUKE UNIV DURHAM NC DEPT OF CHEMISTRY

Personal Author(s):

• Jones, Leonidas J., III
• McPhail, Andrew T.
• Wells, Richard L.

Report Date:

1994-07-18

Pagination or Media Count:

24.0

Abstract:

A major impetus for main group chemists lies in the desire for new precursors to ceramic and electronic materials. As investigators of groups 13-15 compounds, our interest can be attributed to the quest for new precursors to semiconducting materials such as GaAs and InP. An important aspect of this research is ascertaining the fundamental chemistry of these systems in order to synthesize the most efficient precursors for a specific method of deposition. Research in our laboratory has primarily focused on the use of dehalosilylation and salt elimination reactions to form the group 13-15 bonds.

Descriptors:

• *METHYL RADICALS
• *SYNTHESIS
• *ORGANOMETALLIC COMPOUNDS
• *LITHIUM
• *SILICON
• *CHLORIDES
• *ARSENIDES
• *DIMERS
• *INDIUM COMPOUNDS
• METALS
• CRYSTAL STRUCTURE
• NUCLEAR MAGNETIC RESONANCE
• PRECURSORS
• X RAY DIFFRACTION
• SINGLE CRYSTALS
• CHEMICAL BONDS
• SPECTRA
• HYDROCARBONS
• GROUP III COMPOUNDS
• GROUP V COMPOUNDS
• SALTS
• MELTING POINT
• ELIMINATION REACTIONS
• HALOGENS
• ARSENIC COMPOUNDS
• NONMETALLIC COMPOUNDS

Subject Categories:

• Inorganic Chemistry
• Organic Chemistry
• Polymer Chemistry
• Crystallography

Distribution Statement:

APPROVED FOR PUBLIC RELEASE