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New Organometallic Polymeric Materials: The Search for X(2) NLO organometallic Polymers.
Rept. for 1 Jun 93-31 May 94,
UTAH STATE UNIV LOGAN DEPT OF CHEMISTRY AND BIOCHEMISTRY
Pagination or Media Count:
A brief overview of organometallic X2 nonlinear optical NLO polymers is presented. The synthesis of new ferrocene NLO-phores is presented along with their copolymerization with methyl methacrylate to generate organometallic NLO-polymers NLOPs. A new class of organometallic NLO-phores were synthesized by condensation of ferrocene-carboxaldehyde with fluorene compounds. The fluorenyl-ferrocene NLO-phores displayed interesting linear optical properties and reactivity. NLO-spectroscopy was employed to study the orientation and relaxation behavior of the new organometallic NLOPs and we report on these interesting results. NonLinear Optical, Corona Poling, Organometallic Polymers, Ferrocene
APPROVED FOR PUBLIC RELEASE