Accession Number:

ADA277055

Title:

Group 12 Thiolates: Syntheses, Characterization and Decomposition Pathways

Descriptive Note:

Interim rept. 1 Jul 1992-1 Mar 1994

Corporate Author:

GEORGIA INST OF TECH ATLANTA

Report Date:

1994-03-08

Pagination or Media Count:

10.0

Abstract:

Zinc- and cadmium bisalkylthiolate compounds have been prepared and converted into the appropriate binary metal sulfides by thermal treatment. Several mercury chlorothiolates have been synthesized and characterized by single crystal X-ray diffraction. Their decomposition pathways are discussed. The prepared binary metal sulfides have been studied by XRPD and in selected cases - by particle size determination. The volatile co-products have been isolated and characterized by GCMS. Group 12 thiolates, Metal sulfides, Decomposition pathways.

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry
  • Physical Chemistry
  • Nuclear Physics and Elementary Particle Physics

Distribution Statement:

APPROVED FOR PUBLIC RELEASE