Accession Number:

ADA277003

Title:

Tetraalkyldiarsines as Potential Precursors for Electronic Materials: Synthesis and Characterization of Various Iso-Propyl Arsenic Compounds

Descriptive Note:

Interim technical rept. no. 4, 1 Jul 1992-1 Mar 1994

Corporate Author:

GEORGIA INST OF TECH ATLANTA

Report Date:

1994-03-08

Pagination or Media Count:

9.0

Abstract:

Tetrakisiso-propyldiarsine was synthesized by the reaction of i- PrAsLi with i-Pr2Asl. The lithium salt of the secondary arsine was produced following deprotonation of i-Pr2AsH, obtained by reduction of i-Pr2AsI, which was prepared by the thermolysis of i-Pr3AsI2. The X-ray crystal structure of I-Pr3AslI has been determined on the product of the reaction of i-Pr3As and I2. Compounds of the general form E Asi-Pr, E 0, S, Se have been prepared. Organoarsenic chemistry, Isopropyl arsenic compounds, Diarsines.

Subject Categories:

  • Industrial Chemistry and Chemical Processing
  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE