Accession Number:

ADA276923

Title:

Preparation and Characterization of Group 14 Element bis(thiolate) Compounds and Evaluation of Their Potential as Molecular Precursors in the Low Temperature Syntheses of Binary Metal Sulfides

Descriptive Note:

Interim rept. 1 Jul 1992-1 Mar 1994

Corporate Author:

GEORGIA INST OF TECH ATLANTA SCHOOL OF CHEMISTRY AND BIOCHEMISTRY

Report Date:

1994-03-08

Pagination or Media Count:

10.0

Abstract:

Three isomeric lead bisbutylthiolate and tin bisbutylthiolate compounds have been prepared and characterized. Their solid state decomposition, and in the case of the lead bisthiolate compounds, their thermolyses in suspension in a high boiling hydrocarbon, have been studied. X-ray powder diffraction patterns and scanning electron micrographs of the obtained solid state material are discussed. Volatile co-products of the decomposition have been isolated and characterized. Group 14 thiolates, Lead sulfide, Tin sulfide.

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry
  • Polymer Chemistry
  • Optics

Distribution Statement:

APPROVED FOR PUBLIC RELEASE