Silicone Grease as a Precursor to a Pseudo Crown-Ether Ligand: Crystal Structure of (K+)3K(Me2SiO)7+)(HIn(CH2CMe3)3-)4
STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY
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The crystallization of KHInCH2CMe33 from heptane in the presence of silicone grease led to the formation of the title compound, in which one potassium cation is surrounded by a planar cyclo-Me2SiO7 ligand K...O distances range from 2.863 to 2.994A. Indium-hydride, Silicon-oxygen crown ether, X-ray structural study.
- Organic Chemistry
- Physical Chemistry