Accession Number:

ADA276343

Title:

Silicone Grease as a Precursor to a Pseudo Crown-Ether Ligand: Crystal Structure of (K+)3K(Me2SiO)7+)(HIn(CH2CMe3)3-)4

Descriptive Note:

Technical rept.

Corporate Author:

STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY

Report Date:

1994-02-25

Pagination or Media Count:

14.0

Abstract:

The crystallization of KHInCH2CMe33 from heptane in the presence of silicone grease led to the formation of the title compound, in which one potassium cation is surrounded by a planar cyclo-Me2SiO7 ligand K...O distances range from 2.863 to 2.994A. Indium-hydride, Silicon-oxygen crown ether, X-ray structural study.

Subject Categories:

  • Organic Chemistry
  • Physical Chemistry
  • Crystallography

Distribution Statement:

APPROVED FOR PUBLIC RELEASE