Accession Number:

ADA265405

Title:

Synthesis and Properties of Homonuclear, Dimetallic Nickel(II), Copper(II) and Zinc(II) Complexes of p-Xylenediyl and 2-Butynediyl-Bridged Dicyclens

Descriptive Note:

Technical rept. no. 7,

Corporate Author:

STATE UNIV OF NEW YORK AT STONY BROOK DEPT OF CHEMISTRY

Report Date:

1993-05-01

Pagination or Media Count:

14.0

Abstract:

Two new dinucleating ligands have been prepared by linking two 12- aneN4 cyclen macrocycles with either a p-xylenediyl or a 1,4-butanediyl bridge. The nickel II, copper II and zinc II dinuclear complexes have been fully characterized. Their design was intended to be a mimic of the dinuclear hydrolytic enzyme urease which contains two nickel ions in the active site. Catalytic hydrolysis studies are in progress.

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry
  • Physical Chemistry
  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE