Accession Number:

ADA261230

Title:

Intramolecular Bridge/Terminal Oxo Exchange within (MoV2O3)4+ Complexes Containing Linear Oxo Bridges

Descriptive Note:

Interim rept. 1 Jun 1990-Feb 1993

Corporate Author:

PITTSBURGH UNIV PA DEPT OF CHEMISTRY

Report Date:

1993-02-15

Pagination or Media Count:

47.0

Abstract:

Oxo complexes play a central role in the biological and inorganic chemistry of molybdenum. In the 5 oxidation state molybdenum oxo chemistry is dominated by the MoV2O34 unit, which contains a linear oxo bridge which spin pairs two d1 centers while two terminal oxo ligands adopt syn or anti orientations perpendicular to the oxo bridge.

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry
  • Physical Chemistry
  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE