Analysis of the Absorption and Emission Spectra of Mn5+(3d2)in Sr5(PO4) 3Cl
Final rept. Aug 1991-Apr 1992
HARRY DIAMOND LABS ADELPHI MD
Pagination or Media Count:
The absorption and emission spectra of Mn5 3d2 in Sr5PO43C1 are analyzed using a C4 crystal-field Hamiltonian. The descent in symmetry from cubic was guided by it point-charge calculation of the crystal-field components. The calculated energy levels are in excellent agreement with those obtained experimentally. The resulting crystal-field parameters, Bnm, represent very well the crystal-field interactions of Mn5 in Sr5PO43C1. Mn5, strontium chloroapatite, tunable lasers, absorption-emission spectra of Mn5, spectroscopy of MnO4.
- Atomic and Molecular Physics and Spectroscopy