Vibrational Spectrum and Structure of 1,2-Dimethyl-1,2-disila-closo- dodecaborane
MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY
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The IR spectrum thin film of 1,2-dimethyl-1,2-disila-closo- dodecacarborane, DMSB, in the region 200 - 3600 cm-1 and its Raman spectrum solid sample in the region 5 - 3600 cm-1 are reported. It is concluded that the molecular bonding in DMSB is weaker than that in o-carborane. A Raman band at 399 cm-1 is tentatively assigned to the Si-Si bond.
- Organic Chemistry
- Atomic and Molecular Physics and Spectroscopy