Accession Number:

ADA250235

Title:

Vibrational Spectrum and Structure of 1,2-Dimethyl-1,2-disila-closo- dodecaborane

Descriptive Note:

Technical rept.,

Corporate Author:

MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY

Report Date:

1992-04-05

Pagination or Media Count:

12.0

Abstract:

The IR spectrum thin film of 1,2-dimethyl-1,2-disila-closo- dodecacarborane, DMSB, in the region 200 - 3600 cm-1 and its Raman spectrum solid sample in the region 5 - 3600 cm-1 are reported. It is concluded that the molecular bonding in DMSB is weaker than that in o-carborane. A Raman band at 399 cm-1 is tentatively assigned to the Si-Si bond.

Subject Categories:

  • Organic Chemistry
  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE