Charge Motion Effects in Ionic Clusters
STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY
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In ionic clusters the polarization depends on the dynamics of charge delocalization. The polarization follows the charge motion when the characteristic time of motion is much longer than the polarization time adiabatic polarization. For the opposite case diabatic polarization, the polarization is determined by an average field. These two kinds of polarization are considered for the ionic clusters Xe2R and benzene R RHe, Ne, Ar.
- Atomic and Molecular Physics and Spectroscopy