Accession Number:

ADA235576

Title:

(Tertiary-butyl)cyclopentadienylindium(I), In(C5H4CMe3)-Synthesis, Characterization and X-Ray Structural Study

Descriptive Note:

Technical rept.

Corporate Author:

STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY

Personal Author(s):

• Beachleyl, Jr., O. T.
• Lees, J. F.
• Rogers, Robin D.

Report Date:

1991-05-14

Pagination or Media Count:

19.0

Abstract:

The indiumI compound, InC5H4CMe3, has been prepared from the corresponding lithium cyclopentadienyl reagent LiC5H4CMe3 and InC1 in OEt2. Characterization data have included partial elemental analyses C,H, physical properties, IR, 1H NMR and mass spectroscopic data, oxidation reactions with dilute aqueous HC1 and a single-crystal X-ray structural study. The colorless crystal of InC5H4CMe3 consists of infinite zigzag chains. There are no interstrand In...In interactions.

Descriptors:

• *PHYSICAL PROPERTIES
• SINGLE CRYSTALS
• INDIUM COMPOUNDS
• X RAYS
• CHAINS
• OXIDATION REDUCTION REACTIONS
• STRUCTURAL PROPERTIES
• MASS SPECTROSCOPY

Subject Categories:

• Test Facilities, Equipment and Methods

Distribution Statement:

APPROVED FOR PUBLIC RELEASE