Preparation of Inorganic and Organometallic Polymers with Controlled Structures.
Technical rept. no. 27, May 1990-May 1991
CARNEGIE-MELLON UNIV PITTSBURGH PA DEPT OF CHEMISTRY
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Preparative and mechanistic aspects of polysilanes and polyphosphazenes are reviewed based on the several synthetic methods developed in the authors laboratories. Polysilanes are prepared by sonochemical reductive coupling, modifications and ring opening polymerization. Polyphosphazenes are prepared by the catalyzed polycondensation of phosphoranimines and by the direct reaction of phosphonites and phosphinites with silyl azides.
- Polymer Chemistry