Accession Number:

ADA232368

Title:

Synthesis and Characterization of Indium-Arsenic Compounds Containing a Four-Membered In-Ad-In-As or In-As-In-Cl Ring: Crystal Structures of ((Me3SiCH2) 2InAs(SiMe3)2)2 and (Me3SiCH2)2InAs(SiMe3)2In(CH2SiMe3)2Cl

Descriptive Note:

Technical rept.

Corporate Author:

DUKE UNIV DURHAM NC DEPT OF CHEMISTRY

Report Date:

1991-02-25

Pagination or Media Count:

24.0

Abstract:

Recently, organogallium-arsenic compounds containing four-membered rings consisting of mixed-bridging of the gallium atoms by one arsenic atom and one halogen atom have been synthesized via dehalosilyation between an organogallium halide and a silylarsine. Until now, our studies regarding the formation of mixed bridge systems involving the heavier elements of Groups III and V have focused only on gallium and arsenic. In order to investigate the generality of this behavior, analogous reactions utilizing an organoindium halide were carried out.

Subject Categories:

  • Crystallography

Distribution Statement:

APPROVED FOR PUBLIC RELEASE