Diphenylphosphide Derivatives of Bisneopentyl-Gallium and -Indium. Crystal and Molecular Structures of ((Me3CCH2)2GaPPh2)2 and ((Me3CCH2)2InPPh2)3
STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY
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The two compounds, Me3CCH2 2MPPh2 MGa, In have been prepared by metathetical reactions between Me3CCH22MCl and KPPh2 and fully characterized. The characterization data include elemental analyses C,H, melting points, IR, H and P NMR spectral studies, cryoscopic molecular weight studies in benzene solution and single crystal X-ray structural studies. The gallium compound exists as a dimer in benzene solution and in the solid state.
- Organic Chemistry