Accession Number:

ADA229513

Title:

Synthesis and Characterization of Gallium-Arsenic Compounds Containing a Four-Membered Ga-As-Ga-Cl or Ga-AS-Ga-As Ring: Crystal Structures of (Me3SiCH2) 2GaAs(SiMe3)2)2

Descriptive Note:

Technical rept.

Corporate Author:

DUKE UNIV DURHAM NC DEPT OF CHEMISTRY

Report Date:

1990-10-30

Pagination or Media Count:

30.0

Abstract:

The third example of an organogallium four-membered ring compound with arsenic, halogen mixed bridging, Me3SiCH22GaAsSiMe32GaCH2SiMe32CI, was prepared by the reaction of Me3Si3As with two equivalents of Me3SiCH2 2GaC1. X-ray crystallographic analysis showed that the compound contains a nonplanar Ga-As-Ga-C1 ring. The crystals belong to the monoclinic system space group P21c C52h with four molecules per unit cell of dimensions a 12.476, b 15.832, c22.279 A, Beta 108.87, V 41642 A3. The dimer Me3SiCH22GaAsSiMe322 was prepared by reaction of LiAsSiMe32 and Me3SiCH22GaC1. Its solid-state dimeric structure was established by single-crystal X-ray analysis.

Subject Categories:

  • Organic Chemistry
  • Non-acoustic and Non-magnetic Submarine Detection

Distribution Statement:

APPROVED FOR PUBLIC RELEASE