Synthesis and Characterization of (Me3Si)2AsCH2RCH2As(SiMe3)2 (R = CH2, SiMe2) and Ph2GaCl(Ph)2Ga(Me3Si)As(CH2)3As(SiMe3)Ga(Ph)2ClGaPh2
DUKE UNIV DURHAM NC DEPT OF CHEMISTRY
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The synthesis and characterization of Me3Si2AsCH2RCH2AsSiMe32 RCH2 1, SiMe2 2 is described. Compound 1 reacts with four equivalents of Ph2GaCl to Ph2GaClPh2GaMe3SiAsCH23AsSiMe3GaPh2ClGaPh2 3, whose structure was deduced by use of 1H and 13C1H NMR spectroscopy. Keywords Gallium arsenic Bisarsine Synthesis.
- Organic Chemistry