Accession Number:

ADA224945

Title:

Synthesis and Characterization of (Me3Si)2AsCH2RCH2As(SiMe3)2 (R = CH2, SiMe2) and Ph2GaCl(Ph)2Ga(Me3Si)As(CH2)3As(SiMe3)Ga(Ph)2ClGaPh2

Descriptive Note:

Technical rept.

Corporate Author:

DUKE UNIV DURHAM NC DEPT OF CHEMISTRY

Report Date:

1990-07-28

Pagination or Media Count:

14.0

Abstract:

The synthesis and characterization of Me3Si2AsCH2RCH2AsSiMe32 RCH2 1, SiMe2 2 is described. Compound 1 reacts with four equivalents of Ph2GaCl to Ph2GaClPh2GaMe3SiAsCH23AsSiMe3GaPh2ClGaPh2 3, whose structure was deduced by use of 1H and 13C1H NMR spectroscopy. Keywords Gallium arsenic Bisarsine Synthesis.

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE