Spontaneous Decay and Resonance Fluorescence of an Admolecule Near a Silver Surface with Random Roughness
STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY
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The spontaneous decay rate and resonance fluorescence spectrum of a molecule adsorbed near a rough silver surface are calculated. An assumed random distribution of the roughness on the surface is treated as an effective layer. The calculated decay rate is in excellent agreement with experimental measurements. The effects of surface roughness on both the spontaneous decay rate and resonance fluorescence spectrum are discussed for different cases. Keywords Spontaneous decay Resonance fluorescence Admolecule Near silver surface Random roughness.
- Metallurgy and Metallography
- Atomic and Molecular Physics and Spectroscopy