Accession Number:

ADA210888

Title:

The Synthesis and Structure of Novel Antimony Thiametallacycles

Descriptive Note:

Technical rept.

Corporate Author:

MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY

Personal Author(s):

• Buchwald, Stephen L.
• Fisher, Richard A.
• Davis, William M.

Report Date:

1989-08-01

Pagination or Media Count:

16.0

Abstract:

Recently a dramatic resurgence of interest in the organometallic chemistry of the main group elements has occurred. To a large degree this renewed activity derives from the utility of main group compounds in fields such as ceramics, electronic and thermochromic materials, and marine antifouling compounds. The development of general, efficient synthetic methods for the preparation of hitherto inaccessible main group organometallics should greatly enhance progress in many of these fields. In this communication, we report the preparation and characterization of a new class of main group metallacycle, 4, 5-didehydro-2-thiastibolanes, via a transmetallation from zirconium. Chemical synthesis, Organic chemistry.

Descriptors:

• *SYNTHESIS(CHEMISTRY)
• *ANTIMONY COMPOUNDS
• *CYCLIC COMPOUNDS
• *ORGANOMETALLIC COMPOUNDS
• CERAMIC MATERIALS
• CHEMISTRY
• ORGANIC CHEMISTRY
• THERMOCHROMIC MATERIALS
• EFFICIENCY
• ELECTRONIC EQUIPMENT
• MATERIALS
• ZIRCONIUM COMPOUNDS
• HYDROGEN

Subject Categories:

• Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE