Electromagnetic Reaction to Molecular Relaxation and Its Effect on Absorption Near a Rough Surface
STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY
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The effect of electromagnetic reaction to relaxation of a molecule adsorbed on a rough surface is considered. We include the reaction fields due to the system dipole relaxing by both photon radiation and decay to delocalized surface plasmon damping is shown to be important for both small and large-sized roughness features. Keywords Molecular relaxation, Absorption.
- Physical Chemistry
- Radiation and Nuclear Chemistry