Accession Number:

ADA209392

Title:

The Catalytic Hydrolysis of p-Nitrophenyldiphenyl Phosphate in a CTAB (Cetyltrimethylammonium Bromide) Microemulsion

Descriptive Note:

Technical rept. Sep 1986-Oct 1987

Corporate Author:

CHEMICAL RESEARCH DEVELOPMENT AND ENGINEERING CENTER ABERDEEN PROVING GROUND MD

Report Date:

1989-06-01

Pagination or Media Count:

20.0

Abstract:

The iodosobenzoate catalysis of the hydrolysis of p- nitrophenyldiphenyl phosphate in an oil-in-water microemulsion stabilized by cetyltrimethylammonium bromide and 1-butanol has been examined. In addition, we have investigated this hydrolysis in water and in cetyltrimethylammonium chloride micellar solutions. The second-order rate constants for the catalytic and non-catalytic pathways have been determined. Direct tests demonstrate that iodosobenzoate is a turnover catalyst.

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE