Accession Number:

ADA209347

Title:

Modelling the In Situ Infrared Reflection-Absorption Spectra of the Diffuse Layer

Descriptive Note:

Technical rept.

Corporate Author:

CALIFORNIA UNIV DAVIS DEPT OF CHEMISTRY

Report Date:

1989-05-01

Pagination or Media Count:

4.0

Abstract:

Using a stratified medium model for the electrochemical interface and Gouy-Chapman-Stern theory of the double layer, a method to model infrared reflection-absorption spectra of the diffuse layer is developed. This method is applied to spectra obtained in the double layer region for aprotic, organic electrolytes on gold electrodes. Keywords Infrared spectroscopy Raman spectroscopy Electrodeelectrolyte interface Electrochemistry.

Subject Categories:

  • Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE